徐森苗 ,男,特聘人才计划研究员
senmiaoxu@licp.cas.cn
教育经历:
2004.9-2009.7 上海有机化学研究所,博士 (导师:丁奎岭 院士);
2000.9-2004.7 浙江大学化学系,学士
工作经历:
2015.3-现在:中国科学院兰州化学物理研究所开始独立研究工作,特聘人才计划研究员
2013.9-2015.2: 美国波士顿学院化学系博士后(导师:Shih-Yuan Liu 教授);
2010.10-2013.9: 美国俄勒冈大学化学系博士后 (导师:Shih-Yuan Liu 教授);
2009.9-2010.9: 日本京都大学化学系博士后 (导师:Keiji Maruoka 教授)。
研究方向:
催化氧化和新型原子经济性反应,新型配体和催化剂的设计、合成及应用
招生专业: 有机化学专业的硕士、博士研究生,博士后以及职工
代表性研究论文:
1.A. Chrostowska,* S. Xu, A. Maziere, K. Boknevitz, B. Li, E. R. Abbey, A. Dargelos, A. Graciaa, S.-Y. Liu,* UV-Photoelectron Spectroscopy of BN indoles: Experimental and Computational Electronic Structure Analysis. J. Am. Chem. Soc. 2014, 136, 11813−11820.
2.S. Xu, F. Haeffner, L. N. Zakharov, B. Li, S.-Y. Liu,* Monobenzofused 1,4-Azaborines: Synthesis, Characterization, and Discovery of a Unique Coordination Mode. Angew. Chem. Int. Ed. 2014, 53, 6795−6799.
3.S. Xu, T. C. Mikulas, L. N. Zakharov, D. A. Dixon, S.-Y. Liu,* Boron-Substituted 1,3-Dihydro-1,3-azaborines: Synthesis, Structure, and Evaluation of Aromaticity. Angew. Chem. Int. Ed. 2013, 52, 7527−7531.
4.A. Chrostowska,* S. Xu, A. N. Lamm, A. Maziere, C. D. Weber, A. Dargelos, P. Baylere, A. Graciaa, S.-Y. Liu,* UV-Photoelectron Spectroscopy of 1,2 and 1,3-Azaborines: A Combined Experimental and Computational Electronic Structure Analysis. J. Am. Chem. Soc. 2012, 134,10279−10285.
Selected as spotlights in J. Am. Chem. Soc. (2012, 134, 11051)
5.S. Xu, L. N. Zakharov, S.-Y. Liu,* A 1,3-Dihydro-1,3-azaborine Debuts. J. Am. Chem. Soc. 2011, 133, 20152−20155.
6.S. Xu, Z. Wang, X. Zhang, K. Ding,* Asymmetric Baeyer-Villiger Oxidation of 2,3 and 2,3,4-Substituted Cyclobutanones by Chiral Phosphoric Acid with Aqueous H2O2 as the Oxidant. Eur. J. Org. Chem. 2011, 110−116.
7.S. Xu, Z. Wang, X. Zhang, K. Ding,* Charge Transfer Effect on Chiral Phosphoric Acid Catalyzed Asymmetric Baeyer-Villiger Oxidation of 3-Substituted Cyclobutanones Using 30% Aqueous H2O2 as the Oxidant. Chin. J. Chem. 2010, 28, 1731−1735.
8.S. A. Moteki, S. Xu, S. Arimitsu, K. K. Maruoka,* Design and Structurally Rigid trans-Diamine-Based Tf-Amide Organocatalysts with a Dihydroanthracene Frameworks for Asymmetric Conjugate Additions of Heterosubstituted Aldehydes to Vinyl Sulfones. J. Am. Chem. Soc. 2010, 132, 17074−17076.
Highlighted by SynFacts (2011, 216)
9.S. Xu, Z. Wang, Y. Li,* X. Zhang, H. Wang, K. Ding,* Mechanistic Investigation of Chiral Phosphoric Acid Catalyzed Asymmetric Baeyer-Villiger Reaction of 3-Substituted Cyclobutanones with H2O2 as the Oxidant. Chem. Eur. J. 2010, 16, 3021−3035.
10.S. Xu, Z. Wang, X. Zhang, X. Zhang, K. Ding,* Chiral Brönsted Acid Catalyzed Asymmetric Baeyer - Villiger Reaction of 3-Substituted Cyclobutanones by Using Aqueous H2O2. Angew. Chem. Int. Ed. 2008, 47, 2840−2843.
Interviewed by SynForm (2008/6, A63) and Highlighted by SynFacts (2008, 640)