资源化学领域

  

  徐森苗 ,男,研究员 ,博士生导师 

  senmiaoxu@licp.cas.cn  

  教育及工作背景  

  2015.3-至今        中国科学院兰州化学物理研究所, 研究员  

  2013.9-2015.2      美国波士顿学院,博士后(导师:Shih-Yuan Liu 教授)   

  2010.10-2013.9     美国俄勒冈大学,博士后(导师:Shih-Yuan Liu 教授)   

  2009.9-2010.9      日本京都大学,博士后(导师:Keiji Maruoka 教授)  

  2004.9-2010.7      中国科学院上海有机化学研究所,博士 (导师:丁奎岭 院士)   

  2000.9-2004.7      浙江大学,本科(导师:姜玄珍 教授) 

  研究方向:金属有机、不对称催化、有机硼化学 

  招生专业: 有机化学专业的硕士、博士研究生,博士后以及职工  

  获奖及荣誉: 

  2021 JSPS Invitational Fellowship  

  2020 Thieme Chemistry Journals Award  

  代表性研究论文:  

  10. Xie, T.; Chen, L.; Shen, Z.;* Xu, S.*, Simple Ether-Directed Enantioselective C(sp3)-H Borylation of Cyclopropanes Enabled by Iridium Catalysis. Angew. Chem. Int. Ed. 2023, 62, e202300199. 

  9. Gao, Q.; Xu, S.*, Site- and Stereoselective C(sp3)-H Borylation of Strained (Hetero)Cycloalkanols Enabled by Iridium Catalysis. Angew. Chem. Int. Ed. 2023, 62, e202218025. 

  8. Song, S.; Zhou, X.; Ke, Z.;* Xu, S.*, Synthesis of Chiral Sulfoximines via Iridium-Catalyzed Regio-and Enantioselective C-H Borylation: A Remarkable Sidearm Effect of Ligand. Angew. Chem. Int. Ed. 2023, 62, e202217130. 

  7. Shi, Y.; Yang, Y.; Xu, S.*, Iridium-Catalyzed Enantioselective C(sp3)-H Borylation of Aminocyclopropanes. Angew. Chem. Int. Ed. 2022, 61, e202201463. 

  6. Du, R.; Liu, L.; Xu, S.*, Iridium-Catalyzed Regio- and Enantioselective Borylation of Unbiased Methylene C(sp3)-H Bonds at the Position Beta to a Nitrogen Center. Angew. Chem. Int. Ed. 2021, 60, 5843-5847 

  5. Yang, Y.; Chen, L.; Xu, S.*, Iridium-Catalyzed Enantioselective Unbiased Methylene C(sp3)-H Borylation of Acyclic Amides. Angew. Chem. Int. Ed. 2021, 60, 3524-3528. 

  4. Chen, L.; Yang, Y.; Liu, L.; Gao, Q.; Xu, S.* Iridium-Catalyzed Enantioselective α-C(sp3)-H Borylation of Azacycles. J. Am. Chem. Soc. 2020, 142, 12062-12068.  

  3. Shi, Y.; Gao, Q.; Xu, S.*, Chiral Bidentate Boryl Ligand Enabled Iridium-Catalyzed Enantioselective C(sp3)-H Borylation of Cyclopropanes. J. Am. Chem. Soc. 2019, 141, 10599-10604.  

  2. Wang, G.; Liang, X.; Chen, L.; Gao, Q.; Wang, J.-G.; Zhang, P.; Peng, Q.; Xu, S.*, Iridium-Catalyzed Distal Hydroboration of Aliphatic Internal Alkenes. Angew. Chem., Int. Ed. 2019, 58, 8187-8191.  

  1. Zou, X.; Zhao, H.; Li, Y.; Gao, Q.; Ke, Z.; Xu, S.*, Chiral Bidentate Boryl Ligand Enabled Iridium-Catalyzed Asymmetric C(sp2)-H Borylation of Diarylmethylamines. J. Am. Chem. Soc. 2019, 141, 5334-5342. 

  联系方式: 

  E-mail: senmiaoxu@licp.cas.cn 

  课题组主页:https://www.x-mol.com/groups/senmiaoxu 

未经中国科学院兰州化学物理研究所书面特别授权,请勿转载或建立镜像,违者依法必究